High Spin Molecules: [Mn12O12(O2CCH2Cl)16(H2O)4] and the One-electron Reduction Product [PPh4][Mn12O12(O2CCH2Cl)16(H2O)3]
本文档由 labyrinthine 分享于2013-05-25 13:28
The complex of [Mn12O12(O2CCH2Cl)16(H2O)4] was reducedby PPh4I to give a reduced complex [PPh4][Mn12O12-(O2CCH2Cl)16(H2O)3]. Crystal structures of both complexeswere determined by the X-ray method. The dc magnetic susceptibilitymeasurements indicate that the neutral and reducedcomplexes are high spin species.
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